I've probably built over 100 metal tanks, and here's what works for me. I use K&S easy-solder tin (which is tin plated steel) and K&S brass or copper tubing. If the tubes only stick out of the tank a half inch or so, I'll usually use the hard brass or copper; if the tubes stick out enough to reach outside of the fuselage, or especially if the tubes may need to be bent AFTER the tank is built, I'll use the soft brass. I use regular tin/lead rosin core electrical solder, with additional paste flux as required. I tried silver solder such as Sta-Brite and found it to be brittle and prone to cracking. Lately I am using a cheap Hobbico $10.00 pencil type soldering iron with a flat screwdriver-type tip. Surprisingly, I find it gets plenty hot enough.
Start with a wooden block. I've used basswood, pine, maple, and even hard nasty balsa wood. The size and shape of the tank and the size of the available metal will dictate where the seams will be. Typically a tank will have a main body, a front cover, and a back cover. Solder the body together first, then the front cover, then the tubes, then the rear cover. All seams should have an overlapped "flap" of 1/8" to 3/16". The overlapping flaps can be on the inside or the outside of the tank, whatever fits and/or looks best. On the body of the tank, try to have the seam(s) at a corner rather than in the middle of a flat side. Make the holes for the tubes with an awl or ice pick rather than a drill. This creates a bit of a flange for easier soldering. All the tubes should be tack soldered to the inside of the tank. If the tubes are only soldered where they emerge from the tank and not on the inside, cracks can develop from vibration. Once the tank is finished, pressure test it under water and look for leaks, then flush it with dope thinner to remove any soldering flux. With a new tank especially, use a fuel filter to catch any stray material that may work its way out. Actually, always use a fuel filter.
I'm sure that others will have other methods and ideas that will work just as well. I don't think any of it is super critical as long as you get the desired end result. What I will say is don't be afraid to abort and start over if it isn't turning out right. I have found that the more I try to rescue a botched job, the worse it gets and the more time is wasted. I still have to remind myself sometimes....