Randy and all...
I find that giving the 'paint' on the model several days to gas out is a great help, of course. Don't get carried away overcoating the graphics with sealer, Krylon Crystal-Clear, or whatever you're using. Builds up thickness, and that means not only an edge to flat down, but more likely to crack or wrinkle over a curve...
Also, plastic display model builders use an inter-coat liquid - one I found is Micro Set, another may be named Solva-Set - lightly brushed over the area the decal will occupy, just before applying it. A kid's dimestore paintbrush is plenty adequate for that... Label instructions suggest that it softens the film substrate to help it lay down better. When you're happy the decal is settled in as you want, dry the outer surface gently by wiping with a dry Kleenex, and let it sit, undisturbed, for a day or so to get the contact surfaces dry. Once it has done that (depending on the compatibility of the decal sealer with your final gloss top coat material) you should be able to shoot the last coat or so over the model, including decal area.
For larger decals, I squeegee out any air bubbles with a damp Kleenex - working from center out of course - and gently! On severe 3D curves, it may be occasionally needed to punch pinpoint holes around the area.