I don't know about Polyspan, but this works great with silkspan.
I do a couple of coats of Polycrylic on the bare wood, then I wet the silkspan, wring it out so it's just damp, then stick it down with Polycrylic. It has a tendency to want to expand in the Polycrylic, but starting with it damp makes the job easier.
I have no clue how Polyspan would work.