What Larry says is good stuff. My experience is with Esaki silk, some packages which I bought for $1.95 many years ago. If I am doing a diesel powered airplane, I go nitrate all the way. If a glow airplane I go butyrate all the way. I put enough non tautening dope on all surfaces which will touch the silk to make the surface shiny. If you don't do this, the open bays will get shiny and the wood will still show the silk grain because the dope will wick through. I put the silk in place, then wet it. I get it really wet, which is another reason to do a good dope job on the wood. The silk can be stretched tight and the water will hold it in place.
As Larry says, keep the weave straight. Silk is very easy, but you must be patient and demand perfection. Once it is in place, I go around the edges with dope thinned at least 70% thinner. This will adhere to the underlying dope, and blush. If it is a constant chord wing I will demonstrate my expertise
by starting at the bottom trailing edge, going around the leading edge, not sticking to the leading edge, and back to the top trailing edge. I stick it down there and on the ends. Keep everything wet, and hang the wing vertically so the silk dries evenly and does not pull in a warp.
Once dry, I brush on several coats of tautening dope, thinned 70% thinner. This will go through the silk to start, but will not make the puddling effect. I do a couple of panels, then turn over and do a couple of panels. Once most of the pinholes are filled, I go to progressively thicker non tautening dope until it shines to suit me.
If I am going to use tissue numbers and letters, I put them on before going to the thicker coats, just sticking them down with thinner. This presumes you are doing a clear or tinted finish.