I have heard of boiling the props but never understood the reason for it.
The nylon used in the old Top Flite props naturally have water content. One boiled them to restore the water. However, in the late 1980's, early 1990's when they were still being sold, came with a gummed paper label attached to them explaining the boiling method to keep them pliable.
Problem with them was if old, can't tell you what age is old, I guess 10 years old or more, the oils in the plastic dry out and they become brittle. No boiling with help that, they should be tossed.
I never used anything larger than 7 inch diameter, (yellow Tornadoes on sport cross scavenge .10 engine), so can't advise on larger ones used on .15's and up. Flew mostly Cox .049 reed valves and some .020 Pee Wee's 40 - 50 years ago. Then, reason why I bought the T/F white nylons was price. I could buy a 5.25x3 to 6x4 for around $0.35 each. (Best price was the military exchanges and hobby shops.) The Cox competition props were over a dollar. That was a lot more money back then. Even though those the T/F's were notoriously out of balance, I'd sand the back side of the heavier blade to bring into balance. The sport reed valve RPM's aren't as aggressive as Tee Dee's, so probably explains why never had problems with the T/F.
Plus, the T/F's could stand a reasonable amount of punishment, whereas the Cox hard gray were one shot, because I flew over grass. Something as simple as a nose over on landing would break the prop.
I heard for the half-A's, some are experimenting with the more sturdy Chinese electric Bull Nose props for quad small drones. One may want to research in Cox Engine Forums and half-A sections of RCG and RCU for what and where. YMMV (your mileage may vary).