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Author Topic: Shelf Life on Clear Nitrate and Butyrate Dope  (Read 10187 times)

Mike Griffin

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Shelf Life on Clear Nitrate and Butyrate Dope
« on: January 18, 2012, 01:45:37 PM »
Some of you probably know this already but thought I would pass it on for those who may not.  I called Aircraft Spruce and asked them what the shelf life on clear Nitrate and Butyrate dope was.  They did not know so they gave me the number of Certified products and I called them.  Here is what they told me.  Clear Nitrate has a shorter shelf life than Butyrate but essentially they are about the same...2 years.  Something happens to the PH of the product and that is why it turns amber color in the can after about 2 years.  He suggested that I should not use it as the adherence of the product to material is diminished.

Mike

Offline GGeezer

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #1 on: January 18, 2012, 08:04:41 PM »
Hi Mike,
I think those folks are giving you the run around. Ph generally applies to aqueous solutions. Every MSDS sheet on aircraft dopes and lacquers that I've looked at says that Ph is "Not Applicable".
I just opened a formerly unopened new can of Sig Lite Coat and it is as clear as the day it was put in there... I bought it about 20 years ago.
Dope is just plastic resin dissolved in a solvent. There is no chemical reaction curing process that takes place over time. The material returns to its original plastic state by solvent evaporation. If it is kept in an air-tight metal can, away from oxygen and ultra-violet light, it should be good to go in 100 years from now.
This 2 year thing is very self serving on the part of the supplier. He just wants you to chuck your old stuff and buy some new product.

Orv.

Offline John Fitzgerald

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #2 on: January 18, 2012, 08:21:52 PM »
I recently opened a 11 year old can of Sig Lite Coat clear for its first time, and it was good as new.  The can had been kept in the house in a plastic bin with some other modeling supplies the whole time.

Offline larry richards

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #3 on: January 18, 2012, 08:26:32 PM »
I have to agree with Geezer.  For your info, I have 3 gal's of clear nitrate dope in the original USAF green one gallon can's.  Yes it is slightly yellowed.  And it has thickened a little.  I added one pint of thinner to the gallon and it came out just right for brushing.  Infact, that last model of yours that I built and painted in camo was all this same nitrate dope from the USAF.  BTW, these cans are dated 1956!  After numerous flights none of the paint has had any problem.  The color coat over the nitrate is Brodak OD butyrate.  I originally bought 6 gallons of this stuff for $13.00 per gal.  So you can see that you can still use it as long as you keep it cool and in the dark and sealed. I got this stuff from an airport shop in Hayward California that went out of business.  H^^

Mike Griffin

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #4 on: January 18, 2012, 09:10:38 PM »
Well thanks guys.  Looks like the Tech support guy at Certified gave me some bad information. The reason I called was because I had a gallon that is a few years old and had turned Amber Color.  I didn't know if it was still good or not.  You would think that the people who make the stuff would have informed people in their tech department.  I will go ahead and use it... thanks for the feedback.\

Mike

Offline Hoss Cain

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #5 on: January 18, 2012, 09:51:56 PM »
Well thanks guys.  Looks like the Tech support guy at Certified gave me some bad information. The reason I called was because I had a gallon that is a few years old and had turned Amber Color.  I didn't know if it was still good or not.  You would think that the people who make the stuff would have informed people in their tech department.  I will go ahead and use it... thanks for the feedback.\

Mike

Mike, the tech folks are most likely well informed, however they have two responsibilities like make stuff to sell, then sell the stuff they made. In addition, in this screwed-up society of today and marketing situations with resulting liabilities, etc., etc., it's easy to say "....soon..." rather than "....down the road a long way...".  :'(

Well shucks to Larry Richards: He beat me out.  :## I still have, and use some now and then, nitrate dope that I liberated from the USAF in the 1958-1960 time period when I was pulling alert (B-47) on Nouesseiur (sp.?) AFB, Morocco. Oh it has been dark colored for a long time and probably has 3 times the amount of thinner added as original dope in the cans. It brushes over balsa for whatever reason I conjure up to use it.
 Don't blame the guys making the stuff. They just have to repeat what they are told to say like any boss directs.  mw~
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Online Howard Rush

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #6 on: January 18, 2012, 11:56:28 PM »
Bill Byles, who uses as much dope as the rest of us put together, posted something about this recently.   
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Offline David M Johnson

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #7 on: January 19, 2012, 08:05:02 AM »
If the tech was thinking REAL aircraft applications he might be correct. Any A&P guys might be able to confirm that?
David Johnson
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Offline john e. holliday

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #8 on: January 19, 2012, 08:50:19 AM »
I had a quart can of SIG Butyrate Clear that I couldn't remember when I bought it.   Needed some clear and I opened the can.  There was the deep qmber color to it, but it worked well for me.  I used it for base coats on a plane with no problem.   I did have a can of White SIG Butyrate that was pitched as I coud not get the pigment to blend again.   It was like curdled milk. H^^
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Offline Will Hinton

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #9 on: January 19, 2012, 09:42:21 AM »
"If the tech was thinking REAL aircraft applications he might be correct. Any A&P guys might be able to confirm that?"

I once worked for a FBO at Toledo Express who found a fifty-five gallon drum of butyrate that was nearly ten years old.  We were recovering a Colt and needed it, opened it up, thinned it a bit, and went with it.  It worked fine, the Colt was fine, and a buddy and I even got way too many fumes while spraying.  What a headache afterward!!!
These guys posting above are right on with their advise,  full scale or model - makes no difference.
John 5:24   www.fcmodelers.com

Offline billbyles

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #10 on: January 19, 2012, 10:36:18 AM »
Some of you probably know this already but thought I would pass it on for those who may not.  I called Aircraft Spruce and asked them what the shelf life on clear Nitrate and Butyrate dope was.  They did not know so they gave me the number of Certified products and I called them.  Here is what they told me.  Clear Nitrate has a shorter shelf life than Butyrate but essentially they are about the same...2 years.  Something happens to the PH of the product and that is why it turns amber color in the can after about 2 years.  He suggested that I should not use it as the adherence of the product to material is diminished.

Mike

Hi Mike,

Just saw this thread so I went back a few days & copied a posting I wrote that included my experience with shelf life of nitrate & butyrate dope:

"John, buying butyrate dope in small quantities such as pints is the most expensive way to buy it.  For instance, Sig lists butyrate Lite-Coat at $15.99 per pint, and they list it for $26.29 per quart.  That is a little over 50% greater price for twice as much product.  If you buy dope a pint at a time, which is not enough for even one project (at least for me), then it will be very expensive.  For my models I buy butyrate dope a gallon at a time which is much less expensive per unit volume; the dope will keep for a long time if you store it properly.  Always put the lid back on tightly right after you pour some out for use, don't store it where the temperature gets over 100 degrees F, and don't open the can when the humidity gets much over 75% as that will allow moisture to get into the can.  In my full-scale airplane restoration business I have gallon & five gallon containers of butyrate dope that are 15 years old and still work just fine.  The main way that dope deteriorates is to become acidic due to absorbing moisture and/or being stored in the wrong kind of metal container.  You can tell if it has become acidic: the color will become noticeably amber & will have a different smell than when fresh.

The other thing that I do to minimize the cost of dope for my models is to use Randolph butyrate dope for all of the buildup & colors (Randolph offers a huge selection of colors & Aircraft Spruce will send to you a color chart for free), and Sig Lite-Coat for the top coat clear.  Randolph is a very high quality product, however I have found Sig to be more fuel-resistant than any other brand of dope.  For instance, the Aircraft Spruce price for a quart of Randolph A-1690 butyrate dope, non-tautening clear is $14.50.  Randolph 9703 butyrate thinner (which works just fine in Sig or any other butyrate dope) is $8.45 per quart and $25.40 per gallon."

The guys at Consolidated Aircraft Coatings who own Poly-Fiber process, Ceconite process, and Randolph line of paints & dopes as well as other dope products manufacturers will always be conservative when asked about the shelf life of their products.  They are very knowledgeable and honest, but they are giving you the worst case situation.  If some of the dope is, in fact, poured into another container for use, then the original container left to sit with the lid off for a period of time it will lose solvents through evaporation and absorb moisture in a humid atmosphere.  Storing the dope in high temperatures (say, above 100 degrees F), particularly if used under the conditions stated above will lead to deterioration of the dope. 

Another thing that I forgot to mention above is don't use a metal stirring stick; I have several aluminum stirring paddles provided by Sikkens marked with graduations for various ratios for mixing catalyst & reducer that I use with Sikkens polyurethane, but I don't use them with nitrate or butyrate dope.  The metal stick will scratch the coating inside the metal container the dope comes in & lead to the PH change and the dope becoming acidic.  Use a wood stirring stick.

Bill Byles
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So. Cal.

Offline tom hampshire

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #11 on: January 19, 2012, 10:42:59 AM »
Bill do you have any difficulty with getting the lids to seal?  I clean the groove carefully, seat the lid with a light hammer and block of pine or so and then always store the can upside down, so the liquid fills the tiniest cracks.  Is this in line with your experience?

Offline Randy Powell

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #12 on: January 19, 2012, 11:03:30 AM »
I keep my dope in jars generally. I know that I have had colored dope that the solvents had moved along in evaporation. Usually, adding thinner will bring it back, but it depends. If it gets too far along, it will just be jelly.
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Mike Griffin

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #13 on: January 19, 2012, 02:52:00 PM »
Bill thank you very much for reposting that.. I appreciate it very much as well as everyone else's input....

Mike

Offline billbyles

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #14 on: January 21, 2012, 04:35:23 AM »
Bill do you have any difficulty with getting the lids to seal?  I clean the groove carefully, seat the lid with a light hammer and block of pine or so and then always store the can upside down, so the liquid fills the tiniest cracks.  Is this in line with your experience?

Hi Tom,

You are correct in that there can be difficulty in getting the lids to seal if either the lid or the groove have dried dope on them.  I normally punch a couple of small holes in the groove to allow the dope to drain out of the groove & back into the can (Mark Scarborough will know about that) .  Then I put some thinner, acetone, or MEK on a clean rag & clean the remainder out of the groove & off of the lid.  Storing the can upside down isn't a bad idea, either, but I usually don't do that.

I see homebuilders at Chino airport trying to put lids on dope and/or paint cans with an unbelievable buildup of material on the lid and groove just pushing the lid on by hand & then they wonder why the stuff goes bad.  When I mention keeping the can clean they say, usually, "Ah, that's too much trouble - I never do that!"  Then they complain about the high cost of the material and how it takes so much material to do the job...
Bill Byles
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So. Cal.

Offline tom hampshire

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #15 on: January 21, 2012, 07:05:47 AM »
Thanks, Bill.

Bruce Shipp

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #16 on: January 21, 2012, 09:24:36 AM »
So, if  the dope has turned thick and amber, is it still usable?  How can you tell if it is salvageable on not?  I have a gallon of Sig Lite Coat that is very old and has not been opened in 10+ years (still nearly full).  Thanks.

Offline billbyles

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #17 on: January 21, 2012, 10:52:42 AM »
So, if  the dope has turned thick and amber, is it still usable?  How can you tell if it is salvageable on not?  I have a gallon of Sig Lite Coat that is very old and has not been opened in 10+ years (still nearly full).  Thanks.

Bruce,

If the dope has turned thick & amber I would discard it & use another can of product.  When dope has become acidic as indicated by the dark amber color it is not salvageable and best not to be used.  I have used butyrate dope that is 15 + years old that I keep properly stored and has not changed color or odor at all and it works fine.  I just would not risk all of my labor & balsa to try & use dope that has become acidic (which will very likely not adhere very well and probably not flow out very well even when thinned to brushing or spraying viscosity.

Nitrate dope, which I use only on full-scale airplanes because it is an FAA requirement for the first coats down (for cotton, linen, and Ceconite covering processes) and not on my models, tends to deteriorate much quicker than butyrate.  I have discarded a lot of nitrate in my shop, rarely do I have to discard old butyrate.
Bill Byles
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Offline larry richards

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #18 on: January 21, 2012, 11:08:18 AM »
Use it on a test piece of balsa or silkspan and see if there's any problem.  In most cases if you can thin it to the brushing consistancy it's still good to go.   H^^

Mike Griffin

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Re: Shelf Life on Clear Nitrate and Butyrate Dope
« Reply #19 on: January 21, 2012, 12:25:36 PM »
It seems fine Larry.  It is Nitrate but seems to be OK..

Mike

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