You wont accomplish much just polishing the surface on a sprayed catalyzed surface,, you really need to do a "cut and polish" to gain much.
this will remove imperfections,, and texture,, then return it to the sprayed gloss,,
I generally sand with 1500 ( larger imperfections) to 2000 or 2500 WET , generally within a window of 24 to 72 hours from spraying the clear,, assuming normal temp and humidity.
to achieve the "hand rubbed look" , the surface really wants to be flat with no orange peal,, hence the sanding to remove texture,,
as was mentioned, Phil did a nice writeup in Model aviation some time back,, pending that, I plan on covering this in an upcoming installment of my column in Stunt news,, ( once back on my feet)