Okay, here is your treatise on polyspan. This taken from the Classic Aero booklet on how to cover an Aircraft. Since I am told that Polyspan is just very thin Ceconite (polyester fabric) the following may well help you to smooth out your wrinkles. The key is the temperature of the iron. At 250F, it shrinks about half way, ~ 5%, at 350F it shrinks all the way. Above 350F it begins to permanently loosen!! At at about 450F it begins to melt. Also from the manual, "Can I use a heat gun for this? No. You have no idea what temperature you are applying to the fabric. Therein is the reason I use an iron, not a heat gun!.
You can test on a small piece to see if this works. Set the iron to a low temp creep up on to where you can iron out the wrinkles. Could happen well before the Polyspan shrinks very much, then finish shrinking after you cover the wings.
Thus endeth the lesson for today.
p.s. Ceconite can twist a steel tube structure into a pretzel if too high a temp is used.