Okay, I tried the experiment... sort of. It was finally time to cover my Yak-9 wing. I know, I've been yakking about this build since I joined SH, but it's finally time for the end run on it. I checked for twist on the wing skeleton by laying a straight steel rod across the frame against each #9 rib, squinting and eyeballing the two rods to look for any criss-cross. The outboard wing appeared to have a lower angle of attack than the inboard. I gently but firmly twisted and held it at room temp by hand until it was straight. It looked okay, so I applied Monokote to the bottom panels, but did not shrink it tight. A couple of days later I was ready to 'Kote the top, so checked it again and the twist had returned.
Since I didn't want to moisten the bones immediately before sealing it up, I went with one of the suggestions above; that heat does the work, and steam mainly helps expedite the job by spreading the heat faster. The LE is epoxied and glassed at the center joint. I put a hair dryer on the table and held the wing in front of it while counter-twisting the wing and focusing the air on the LE joint and center sheeting for 5 minutes. I held it in that position until it cooled and re-checked. My rods showed no more criss-cross, lined up perfectly. I left it on the table for about 12 hours and re-checked, still perfect. So I covered the top panels and tightened it with the iron starting at the #1 bays(top and bottom), and tightened each bay top, bottom, inboard and out, all the way down. I never use the gun, just an iron with no sock. It came out great. (I might be a Monokote idiot savant)
Now I don't know for sure if I reconfigured the wood, or just the epoxy, but in any case, thanks to this thread, I now have as straight of a wing as I have ever built. So for my next two projects, I still have twisted wood, both fuselage stock, and will try the same thing
with steam and report my findings.
Thanks for putting ideas in my head from which I can cherry pick the ones that fit my own puzzle(that's how to best use a forum, right). Oh, and bye the way, the closest thing to a jig I used on this wing was a bunch of square blocks, some of them slotted to accept the TE sticks, pins, divider caliper, and a ruler. I guess that really was a jig though, wasn't it. :p
You crazy people will help me become a better builder yet!

Rusty