I've had it happen to some really old cans and jars of dope, both Brodak and SIG. Whenever I think about it, I turn my cans and jars over. Flipping them about every two months. Don't know if that helps or not, but I have plenty of stock I've had for more than 20 years that is still good. I've never purchased a gallon of anything except when covering and painting a real plane.