I'm currently using up fuel that I bought about 20 years ago. It was stored in a northern basement, cool, dark, but not always dry. Sig fuel, in the plastic jugs. I've burned 5 gallons so far, with 5 more gallons to go. Engines run fine, and I haven't had any paint problems with an old Sig doped plane or newer doped finishes.
I would suspect paint trouble, not fuel trouble.