I use liquid flux to build tanks. Why? I simply lose the will to breath when I try super polishing the metal clean and dicking about with core solder. ( It kind of works , but I'd rather do something else than struggle with trying to glue bits of metal together with blobs of mercury that don't flow)
I am not sure what kinds of solder or material you are attempting to use but I have had no problem building 100's of tanks with "core solder" - by which I presume you mean rosin core solder. And I am not sure what you think you need to do extensive surface prep, you basically take the tin out of the package and start soldering. It flows out easily with very little heat and I have and many others have made tanks with as little as a 15-watt uncontrolled electronics iron, mine acquired from a convenience store and costing about $5 in 1971.
Additionally, while you might have had some problem with 50/50 solder or RoHS solder (not recommended), it is quite literally impossible to get "blobs of mercury that don't flow" with 63/37, there is no "plastic phase" to speak of, so it can't blob up without a concerted effort.
There are moderately safe liquid fluxes (i.e. safe from corrosion), they are more-or-less just rosin just like in the core of rosin-core solder. The less-safe versions all have a tendency top corrode the tank, to the point that tanks can simply corrode away even after extensive flushing with water/alcohol/lacquer thinner and glow fuel. I am not sure what "meths" might be, maybe methyl alcohol (methanol). Even something mild like Nokorode should be named soemthing like "less corrode" because while it is about the mildest paste flux you can easily get, it still causes ferrous metal to rust in short order.
Obviously you can do as you please, but I would very hesitant to recommend almost any liquid or paste flux for tanks, it is just not necessary and more-or-less gaurantees a problem later with corrosion.
Brett