Yes, that's exactly what happens (sometimes). The fuel heats up, gets thinner, and makes the engine go rich.
Brett
What Brett says, is what happened with one of my header muffler equipped planes. Not until I installed a balsa spacer and aluminum foil faced ply heat shield, between the tank and header muffler, did I get good runs with the engine.
Prior to adding the balsa shim and heat shield the top nose section of the plane would be really warm, and the spinner "very" warm after a flight. At times after a flight, raw fuel would spit out the tank vent a few moments after landing.
After the addition of the balsa shim and heat shield, the top nose section of the plane is same temp as the rest of the plane, the spinner is cool to the touch, and no fuel is ejected from the vent tube.
Flying the plane without the cowl things worked fine. Flying with the cowl presented heat problems. I opened the hot air exits on four separate occasions with little gain each time. The cure was adding the balsa shim and heat shield.
Good luck;
Larry