You can remove the head and put something, like a thin steel ruler, to the baffle slot. Then look again from the direction of fins. They shouldn't be parallel.
But propably nothing to worry about, most propably the bolt holes and groove are all cut during same operation. L
Well, that would mean the slot is crooked WRT the piston baffle. Most of these sort of engines I have seen have the baffle clearance slot cast in, rather than machined in. Many have the head fins made that way, too, and only the tenon, mating surface, and diameter are machined. I would put some modeling clay on the bottom of the head, bolt it down, and then run the piston into it, and see if it's crooked or not. But, it doesn't matter because you can't really fix it. Just run it and see, if it's not OK, then try to figure something out.
I actually have an idea how it might be "fixed", but it's so hacky I don't want to say it in public.
Brett