There are actually three sets of windings, and they can be hooked up in two configurations--a delta -- /_\ -- (you get the idea---the three output wires are connected to the corners, and a "Wye" -- Y --.
In the delta configuration, measuring the current between any two wires measure a resistance =1/(1/R +1/2R)=2/3R, where R=resistance of any one leg.
In the Wye configuration, the resistance between any two wires is just 2R (same meaning for R). I will mention that the kV of the Wye is ~1.7 (sqrt(3) times larger than Delta.
Basically the "3"'s cancel out which means the Wye and delta really have the same efficiency in the end. To get the same kV, the Wye will have fewer winds, which in the end has less resistance. There are some differences in the ways the currents circulate, but as far as I have figured out, there doesn't seem to be any major advantage to either configuation.
However if you want to change kV, one way to do it is by changing the termination. I had wound a 3014 and gotten a kV of ~1200 rpm/volt---too high. I changed the delta to Wye and then had a kV of 725 rpm/volt. Unfortunately for me the 1200 was too high for 3s and the 725 too low for 4s! Oh well.