In thinking about this, that O-ring is a seal against air leaking in. Crankcase vacuum is what draws fuel to the NVA and past the point where the needle regulates the flow, and then on up to the venturi, etc. Any fuel would have to be under some kind of pressure, make it's way up the inside where the needle passes, and out onto the threaded external part of the NVA.
So, exposure to *air* caused it to swell up and jam?
O-rings do not just swell up and jam exposed to either air, or normal commercial model fuel components. Therefore it was exposed to things not normally in model fuel. Given that this is home-brew fuel with unknown sources of the constituents, and it *consistently doesn't run properly* as suggested by innumerable previous threads, many of which contain discussions about obscure fuel additives, it could have lots of other things that DO cause o-rings to swell up, the most sensible way to eliminate the fuel as a source of problems is to get a commercial fuel of known quality.
What does not make sense is to take a known-good part, and then start modifying it, changing materials, to try to "work around" whatever other problem is present, because there is absolutely nothing wrong with the part as it comes from the factory. That's stacking a kludge on top of an existing problem. Of course, the next step is to "replace the crummy rear needle with a good ST spraybar", which stacks yet another change, now you have to also change the venturi, or the engine suddenly loses 20% of the power, and also induces the potential for more problems with the known "tuning fork effect".
That's how these things spiral out of control. The fact that a presumably stock part, known to be good, is getting jammed up tells you beyond any reasonable doubt that there is something odd about the fuel, because that's the only thing this o-ring is exposed to that could conceivably cause it. That's a problem that needs to be fixed, forget anything else, before proceeding to the next step, because whatever it is might also be causing the systematic low power and odd run characteristics that Frank has been experiencing, well, forever.
Of course, as always, it's just advice, no one is compelled to listen or act on it.
The red flags don't wave any more wildly than this.
Brett